A new type of intramolecular H ⋯ H ⋯ H interaction involving N–H ⋯ H(Ir)⋯ H–N atoms. Crystal and molecular structure of [IrH(η1-SC5H4NH)2(η2-SC5H4N)(PCy3)]BF4·0.72CH2Cl2-Reference-Cited by-同舟云学术

A new type of intramolecular H ⋯ H ⋯ H interaction involving N–H ⋯ H(Ir)⋯ H–N atoms. Crystal and molecular structure of [IrH(η1-SC5H4NH)2(η2-SC5H4N)(PCy3)]BF4·0.72CH2Cl2

Published:1994 Issue:19 Volume: Page:2201-2202
ISSN:0022-4936
Container-title:J. Chem. Soc., Chem. Commun.
language:en
Short-container-title:J. Chem. Soc., Chem. Commun.

Author:

Park Sunghan,Ramachandran Ravindranath,Lough Alan J.,Morris Robert H.

Publisher

Royal Society of Chemistry (RSC)

Subject

Molecular Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940002201

Reference11 articles.

1. Complexation of an amide to iridium via an iminol tautomer and evidence Ir–H ⋯ H–O hydrogen bond

2. Reactions of transition metal dihydrogen complexes

3. Rhodium(III) complexes with pyridine-2-thiol (pySH) and pyridine-2-thiolato (pyS) as the only ligands: crystal structures of mer-[Rh(pyS)3], [Rh(pyS)2(pySH)2]Cl·0.5H2O, and [Rh(pyS)3(pySH)]

4. Assessment of the "T1 criterion" for distinguishing between classical and nonclassical transition-metal hydrides: hydride relaxation rates in tris(triarylphosphine)osmium tetrahydrides and related polyhydrides

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