Synthesis and structural characterisation of [(pta)3Au]2Au2(i-mnt)2·0.5Me2Co·0.5MeCN; an example of unsupported AuI⋯ AuIinteractions with [Au(pta)3]+, giving a non-linear tetranuclear chain {pta = phosphatriazaadamantane, i-mnt =[S2C2(CN)2]2–}
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940000431
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1. Gold Chemistry is Different
2. Structures of bis(triphenylphosphine)gold(I) hexafluorophosphate, [Au(PPh3)2]PF6 (1), and bis(triphenylphosphine)gold(I) nitrate, [Au(PPh3)2]NO3 (2)
3. Is regular tetrahedral geometry possible in gold(I)–phosphine complexes? X-Ray crystal structures of three modifications of (PPh3)4Au+BPh4–
4. A novel three-co-ordinate Di-gold(I) diphosphine complex [Au2(Me2PCH2PMe2)3](BF4)2 0.5C7H8: X-ray crystal and molecular structure
5. Syntheses and x-ray structural characterizations of three-coordinate gold(I) and silver(I) complexes with the potentially tetradentate ligand tris(2-(diphenylphosphino)ethyl)amine (NP3): [Au2(NP3)2](BPh4)2, Au(NP3)PF6, Au(NP3)NO3, Ag(NP3)NO3, and Ag(NP3)PF6. The Au(I) compounds are luminescent
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