A d10 Ag(i) amine–borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuum-Reference-Cited by-同舟云学术

A d10 Ag(i) amine–borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuum

Published:2019 Issue:26 Volume:48 Page:9776-9781
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Johnson Alice¹²³⁴⁵^ORCID,Martínez-Martínez Antonio J.¹²³⁴⁵^ORCID,Macgregor Stuart A.⁶⁷⁸⁵^ORCID,Weller Andrew S.¹²³⁴⁵^ORCID

Affiliation:

1. Chemistry Research Laboratories

2. Department of Chemistry

3. University of Oxford

4. Oxford

5. UK

6. Institute of Chemical Sciences

7. Heriot Watt University

8. Edinburgh EH14 4AS

Abstract

The bonding in H₃B·NMe₃ σ-complexes of d⁸-Rh(i) and d¹⁰-Ag(i) show subtle differences, as probed by structural, spectroscopic and computational studies.

Funder

Engineering and Physical Sciences Research Council

SCG Chemicals

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00971J

Reference37 articles.

1. The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers

2. Coordination Compounds of Monoborane−Lewis Base Adducts: Syntheses and Structures of [M(CO)5(η1-BH3·L)] (M = Cr, Mo, W; L = NMe3, PMe3, PPh3)

3. Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

4. Amine-Borane Dehydropolymerization: Challenges and Opportunities

5. Recent advances in transition metal catalysed dehydropolymerisation of amine boranes and phosphine boranes

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