Stereodivergent synthesis of alkenes by controllable syn-/anti-fragmentation of β-hydroxysulfonyl intermediates
Author:
Affiliation:
1. Faculty of Chemistry
2. University of Warsaw
3. 02-093 Warsaw
4. Poland
Abstract
Complementary fragmentation mechanisms of Hawkins and one-pot Julia olefinations were employed for the stereodivergent synthesis of alkenes.
Funder
Narodowe Centrum Nauki
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01563A
Reference22 articles.
1. Olefination of carbonyl compounds: modern and classical methods
2. The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects
3. The Wittig and Related Reactions in Natural Product Synthesis
4. New developments in the Peterson olefination reaction
5. The modified Julia olefination: alkene synthesis via the condensation of metallated heteroarylalkylsulfones with carbonyl compounds
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