Trichloroacetonitrile as an efficient activating agent for the ipso-hydroxylation of arylboronic acids to phenolic compounds

Author:

Fang Yuanding12345,Zhao Rong12345,Yao Yuan56274,Liu Yang56274,Chang Denghu12345,Yao Ming89104,Shi Lei891041ORCID

Affiliation:

1. School of Science

2. Harbin Institute of Technology

3. Shenzhen

4. China

5. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage

6. School of Chemistry and Chemical Engineering

7. Harbin 150001

8. Hubei Key Laboratory of Drug Synthesis and Optimization

9. Jingchu University of Technology

10. Jingmen

Abstract

An efficient and practical method for the ipso-hydroxylation of arylboronic acids was developed using TBHP and Cl3CCN under base-free conditions with blue-LED irradiation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Harbin Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference72 articles.

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2. V. Cornel and C. J.Lovely , “Boron Trifluoride Etherate” in the Encyclopedia of Reagents for Organic Synthesis , John Wiley & Sons. , New York, USA , 2007

3. FLP catalysis: main group hydrogenations of organic unsaturated substrates

4. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

5. Frustrated Lewis Pair Chemistry: Development and Perspectives

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