Copper-catalyzed acyloxylation of the C(sp3)–H bond adjacent to an oxygen by a cross-dehydrogenative coupling approach-Reference-Cited by-同舟云学术

Copper-catalyzed acyloxylation of the C(sp3)–H bond adjacent to an oxygen by a cross-dehydrogenative coupling approach

Published:2014 Issue:92 Volume:4 Page:50795-50800
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Raju Kammari Bal¹²³,Kumar Bejjanki Naveen¹²³,Nagaiah Kommu¹²³

Affiliation:

1. Organic & Biomolecular Chemistry Division

2. CSIR–Indian Institute of Chemical Technology

3. Hyderabad, India

Abstract

We demonstrated a dehydrogenative cross coupling between a benzyl alcohol and C(sp³)–H bond for the construction of a C–O bond. This method reveals a new strategy for the direct use of benzyl alcohols in the synthesis of esters with the use of copper as a catalyst and TBHP as an oxidant.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA06233G

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