Radical non-radical states of the [Ru(PIQ)] core in complexes (PIQ = 9,10-phenanthreneiminoquinone)-Reference-Cited by-同舟云学术

Radical non-radical states of the [Ru(PIQ)] core in complexes (PIQ = 9,10-phenanthreneiminoquinone)

Published:2016 Issue:19 Volume:45 Page:8236-8247
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bera Sachinath¹²³⁴,Maity Suvendu¹²³⁴,Weyhermüller Thomas⁵⁶⁷,Ghosh Prasanta¹²³⁴

Affiliation:

1. Department of Chemistry

2. R. K. Mission Residential College

3. Kolkata-103

4. India

5. Max-Planck-Institut für Chemische Energiekonversion

6. D-45470 Mülheim

7. Germany

Abstract

The electronic states of types [Ru^II(PIQ˙⁻)], [Ru^III(PIQ˙⁻)], [RuIII2(PIQ˙⁻)₂], [RuIII2(PIQ˙⁻)(PIQ)] and [Ru^III(PIQ)] (PIQ = 9,10-phenanthreneiminoquinone) were substantiated by the single crystal X-ray structure determinations, EPR spectra, cyclic voltammetry, DFT calculations and compared with those of 9,10-phenanthrenequinone (PQ) analogues.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00091F

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