Remarkable reactivity of a rhodium(i) boryl complex towards CO2 and CS2: isolation of a carbido complex-Reference-Cited by-同舟云学术

Remarkable reactivity of a rhodium(i) boryl complex towards CO2 and CS2: isolation of a carbido complex

Published:2015 Issue:78 Volume:51 Page:14613-14616
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kalläne Sabrina I.¹²³⁴,Braun Thomas¹²³⁴,Teltewskoi Michael¹²³⁴,Braun Beatrice¹²³⁴,Herrmann Roy¹²³⁴,Laubenstein Reik¹²³⁴

Affiliation:

1. Humboldt-Universität zu Berlin

2. Department of Chemistry

3. D-12489 Berlin

4. Germany

Abstract

The activation of CO₂, CS₂ as well as of PhNCO at [Rh(Bpin)(PEt₃)₃] (pin = pinacolato) by CX bond cleavage is reported. With CS₂ a unique binuclear μ-carbido complex was generated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC05606C

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