σ-Hole⋯π and lone pair⋯π interactions in benzylic halides-Reference-Cited by-同舟云学术

σ-Hole⋯π and lone pair⋯π interactions in benzylic halides

Published:2015 Issue:22 Volume:13 Page:6194-6202
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Montoro Teresa¹²³,Tardajos Gloria⁴⁵⁶⁷³,Guerrero Andrés⁴⁵⁶⁷³,Torres María del Rosario⁸⁵⁶⁷³,Salgado Cástor⁹¹⁰⁷³,Fernández Israel⁹¹⁰⁷³,Osío Barcina José⁹¹⁰⁷³

Affiliation:

1. EUIT Forestales

2. Universidad Politécnica de Madrid

3. Spain

4. Departamento de Química Física

5. Facultad de Ciencias Químicas

6. Universidad Complutense de Madrid

7. 28040 Madrid

8. Laboratorio de difracción de Rayos X

9. Departamento de Química Orgánica

10. Facultad de Ciencias Químicas. Universidad Complutense de Madrid

Abstract

Depending on the relative orientation of the halogen atom and the phenyl ring, the benzylic halides studied show “classical” halogen⋯π bonds as well as intramolecular interactions without σ-hole participation based on n → π* (LP⋯π) interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00366K

Reference101 articles.

1. Halogen Bonding: Fundamentals and Applications, of Structure and Bonding, Vol. 126, ed. P. Metrangolo and G. Resnati, Springer, Berlin, 2008

2. Halogen Bonding in Supramolecular Chemistry

3. Halogen Bonding: Where We Are and Where We Are Going

4. Halogen bonding: an electrostatically-driven highly directional noncovalent interaction

5. Halogen Bonding: An Interim Discussion

Cited by 17 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Supramolecular architectures sustained by delocalised C–I⋯π(arene) interactions in molecular crystals and the propensity of their formation;CrystEngComm;2021

2. Computational and experimental evidence of N–H…π and cooperative πN…π∗ interactions in pyrrole…benzene and pyrrole…ethylene heterodimers at low temperatures;Journal of Molecular Structure;2020-06

3. Maxwell-Boltzmann statistics applied in the study of photoluminescent emission bands in the (S)-(-)-1-(4-bromophenyl)-N-1,2,3,4-(tetrahydro-1-naphthyl)methanimine organic crystals;Optical Materials;2019-10

4. Supramolecular Tessellations by a Rigid Naphthalene Diimide Triangle;Journal of the American Chemical Society;2019-09-17

5. Adenine as a Halogen Bond Acceptor: A Combined Experimental and DFT Study;Crystals;2019-04-25