Divergent reaction pathways in gold-catalyzed cycloisomerization of 1,5-enynes containing a cyclopropane ring: dramatic ortho substituent and temperature effects-Reference-Cited by-同舟云学术

Divergent reaction pathways in gold-catalyzed cycloisomerization of 1,5-enynes containing a cyclopropane ring: dramatic ortho substituent and temperature effects

Published:2016 Issue:7 Volume:7 Page:4318-4328
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chen Gen-Qiang¹²³⁴⁵,Fang Wei¹²³⁴⁵,Wei Yin¹²³⁴⁵,Tang Xiang-Ying¹²³⁴⁵,Shi Min¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. P. R. China

Abstract

Gold-catalyzed cycloisomerization of 1,5-enynes containing a cyclopropane ring provides access to cyclobutane-fused 1,4-cyclohexadiene, 1,3-cyclohexadiene, tricyclic cyclobutene and biscyclopropane derivatives.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00058D

Reference144 articles.

1. Enantioselective, transition metal catalyzed cycloisomerizations

2. Catalytic skeletal reorganization of enynes through electrophilicactivation of alkynes: double cleavage of C–C double and triple bonds

3. Recent advances in syntheses of carbocycles and heterocycles via homogeneous gold catalysis. Part 2: Cyclizations and cycloadditions