Enabling a bioinspired N,N,N-copper coordination motif through spatial control in UiO-67: synthesis and reactivity

Author:

Gerz Isabelle12ORCID,Aunan Erlend S.12ORCID,Finelli Valeria34ORCID,Abu Rasheed Mouhammad12ORCID,Deplano Gabriele3ORCID,Cortez S. P. Rafael12ORCID,Schmidtke Inga L.125ORCID,Wragg David S.12ORCID,Signorile Matteo3ORCID,Hylland Knut T.12ORCID,Borfecchia Elisa3ORCID,Lillerud Karl Petter12,Bordiga Silvia3ORCID,Olsbye Unni12ORCID,Amedjkouh Mohamed12ORCID

Affiliation:

1. Department of Chemistry, University of Oslo, P. O. Box 1033 Blindern, N-0315 Oslo, Norway

2. Centre for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1126 Blindern, N-0316 Oslo, Norway

3. Department of Chemistry, NIS and INSTM Reference Centre, Università di Torino, Via G. Quarello 15/A, I-10135, and Via P. Giuria 7, I-10125, Turin, Italy

4. University School for Advanced Studies, IUSS Pavia, Palazzo del Broletto, Piazza della Vittoria 15, I-27100, Pavia, Italy

5. Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, University of Oslo, N-0315 Oslo, Norway

Abstract

The incorporation of a novel N,N,N-linker into UiO-67 permits it to coordinate copper in an otherwise unattainable way.

Funder

European Research Council

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

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