Construction of methylene-bridged electron-deficient corona[<i>n</i>]arenes and selective fluoride recognition through anion

Construction of methylene-bridged electron-deficient corona[n]arenes and selective fluoride recognition through anion–π interactions

Published:2023 Issue:6 Volume:10 Page:1405-1411
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Guo Shen-Yi¹^ORCID,Tong Shuo¹^ORCID,Guo Qing-Hui²^ORCID,Wang Mei-Xiang¹^ORCID

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (MOE), Department of Chemistry, Tsinghua University, Beijing 100084, China

2. Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou, 310027, China

Abstract

Despite significant development of the nascent anion–π interactions in recent years, the noncovalent interactions between fluoride ion, a unique anion species, and electron-neutral aromatic rings remain rare and even controversial.

Funder

National Natural Science Foundation of China

Tsinghua University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00024A

Reference48 articles.

1. Fluorescence and Colorimetric Chemosensors for Fluoride-Ion Detection

2. Insights into the binding aspects of fluoride with neutral synthetic receptors

3. Recent advances in selective recognition of fluoride with macrocyclic receptors

4. Anion–π Interactions: Do They Exist?

5. Anion−Aromatic Bonding: A Case for Anion Recognition by π-Acidic Rings

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