Experimental and theoretical studies of the rhodium(<scp>i</scp>)-catalysed C–H oxidative alkenylation/cyclization of<i>N</i>-(2-(methylthio)phenyl)benzamides with maleimides-Reference-Cited by-同舟云学术

Experimental and theoretical studies of the rhodium(i)-catalysed C–H oxidative alkenylation/cyclization ofN-(2-(methylthio)phenyl)benzamides with maleimides

Published:2023 Issue:7 Volume:10 Page:1617-1625
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Skhiri Aymen¹^ORCID,Taborosi Attila²³^ORCID,Ohara Nozomi¹,Ano Yusuke¹^ORCID,Mori Seiji²⁴^ORCID,Chatani Naoto¹⁵^ORCID

Affiliation:

1. Department of Applied Chemistry, Osaka University, Suita, Osaka 565-0871, Japan

2. Institute of Quantum Beam Science, Ibaraki University, Mito, Ibaraki 310-8512, Japan

3. Research Initiative for Supra-Materials, Shinshu University, Nagano, Nagano 380-8553, Japan

4. Frontier Research Center for Applied Sciences, Ibaraki University, Tokai, Ibaraki 319-1106, Japan

5. Research Center for Environmental Preservation, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

We presented the synthesis of isoindolone spirosuccinimidesviathe Rh(i)-catalysed reaction of aromatic amides that contain a (2-methylthio)aniline directing group with maleimides. Several possible reaction paths were examined by DFT calculations.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00023K

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