On the ionizing properties of supercritical carbon dioxide: uncatalyzed electrophilic bromination of aromatics-Reference-Cited by-同舟云学术

On the ionizing properties of supercritical carbon dioxide: uncatalyzed electrophilic bromination of aromatics

Published:2014 Issue:92 Volume:4 Page:51016-51021
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Delgado-Abad Thais¹²³,Martínez-Ferrer Jaime¹²³,Reig-López Javier¹²³,Mello Rossella¹²³,Acerete Rafael¹²³,Asensio Gregorio¹²³,González-Núñez María Elena¹²³

Affiliation:

1. Departamento de Química Orgánica

2. Universidad de Valencia

3. 46100-Burjassot, Spain

Abstract

scCO₂, a non-polar solvent with a dielectric constant lower than n-pentane, promotes the electrophilic bromination of aromatics as efficiently as strongly ionizing solvents such as aqueous acetic and trifluoroacetic acids.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA10557E

Reference82 articles.

1. Handbook of Green Chemistry, Supercritical Solvents, ed. W. Leitner and P. G. Jessop, Wiley-VCH, New York, 2010, vol. 4

2. Green Chemistry Using Liquid and Supercritical Carbon Dioxide, ed. J. M. DeSimone and W. Tumas, Oxford University Press, Oxford, 2003

3. Supercritical and near-critical CO2 in green chemical synthesis and processing

4. The Potential of Carbon Dioxide in Synthetic Organic Chemistry

5. C. Reichardt and T.Welton, Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH, Weinheim, 4th edn, 2011

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Highly Efficient and Practical Oxidative Bromination of Electron-Rich Arenes Using S-Methyl Methanethiosulfonate as the Oxidant;Synlett;2024-04-26

2. The electrophilic aromatic bromination of benzenes: mechanistic and regioselective insights from density functional theory;Physical Chemistry Chemical Physics;2023

3. Development of Novel Silicon-Based Thickeners for a Supercritical CO2 Fracturing Fluid and Study on Its Rheological and Frictional Drag Behavior;Energy & Fuels;2020-11-17

4. Synthesis of 5-phenoxyisobenzofuran-1(3H)-one as a key intermedate of the drug roxadustat;Tetrahedron Letters;2020-08

5. Photoiodocarboxylation of Activated C═C Double Bonds with CO2 and Lithium Iodide;The Journal of Organic Chemistry;2018-10-10