A substituentpara-to-orthopositioning effect drives the photoreactivity of a dibenzothiophene-based oxalate series used as LED-excitable free radical photoinitiators-Reference-Cited by-同舟云学术

A substituentpara-to-orthopositioning effect drives the photoreactivity of a dibenzothiophene-based oxalate series used as LED-excitable free radical photoinitiators

Published:2019 Issue:13 Volume:10 Page:1599-1609
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Pan Haiyan¹²³⁴⁵^ORCID,Chen Siqi¹²³⁴⁵,Jin Ming¹²³⁴⁵^ORCID,Malval Jean-Pierre⁶⁷⁸⁹¹⁰,Wan Decheng¹²³⁴⁵^ORCID,Morlet-Savary Fabrice⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Polymer Materials

2. School of Materials Science and Engineering

3. Tongji University

4. Shanghai

5. P.R. China

6. Institute de Science des Matériaux de Mulhouse

7. UMR CNRS 7361

8. Université de Haute-Alsace

9. Mulhouse

10. France

Abstract

Dibenzothiophene-based oxalate derivatives were synthesized as type I photoinitiators, and their photoinitiation properties depend on the substituentpara-to-orthopositioning effect of the oxalates.

Funder

National Natural Science Foundation of China

Tongji University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2019/PY/C9PY00052F

Reference61 articles.

1. From small molecules to polymer fibers: Photopolymerization with electrospinning on the fly

2. α-hydroxyalkyl ketones derivatives used as photoinitiators for photografting field