A substituentpara-to-orthopositioning effect drives the photoreactivity of a dibenzothiophene-based oxalate series used as LED-excitable free radical photoinitiators
Author:
Affiliation:
1. Department of Polymer Materials
2. School of Materials Science and Engineering
3. Tongji University
4. Shanghai
5. P.R. China
6. Institute de Science des Matériaux de Mulhouse
7. UMR CNRS 7361
8. Université de Haute-Alsace
9. Mulhouse
10. France
Abstract
Dibenzothiophene-based oxalate derivatives were synthesized as type I photoinitiators, and their photoinitiation properties depend on the substituentpara-to-orthopositioning effect of the oxalates.
Funder
National Natural Science Foundation of China
Tongji University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2019/PY/C9PY00052F
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