Effects of complexation with sulfuric acid on the photodissociation of protonated Cinchona alkaloids in the gas phase-Reference-Cited by-同舟云学术

Effects of complexation with sulfuric acid on the photodissociation of protonated Cinchona alkaloids in the gas phase

Published:2019 Issue:28 Volume:21 Page:15439-15451
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ben Nasr Feriel¹²³⁴⁵,Alata Ivan¹²³⁴⁵,Scuderi Debora³⁶⁷⁸⁹^ORCID,Lepère Valeria¹²³⁴⁵,Brenner Valerie¹⁰¹¹²¹²⁹^ORCID,Jaïdane Nejm-Eddine¹³¹⁴¹⁵¹⁶¹⁷,Zehnacker Anne¹²³⁴⁵^ORCID

Affiliation:

1. Institut des Sciences Moléculaires d’Orsay (ISMO)

2. CNRS

3. Univ. Paris-Sud

4. Université Paris-Saclay

5. F-91405 Orsay

6. Laboratoire de Chimie Physique

7. UMR 8000, and CNRS

8. Orsay

9. France

10. LIDYL

11. CEA

12. F-91191 Gif-sur-Yvette

13. Laboratoire de Spectroscopie Atomique

14. Moléculaire et Applications (LSAMA) Université de Tunis El Manar

15. LSAMA

16. Tunis 1060

17. Tunisia

Abstract

The complex formed between Cinchona alkaloids and sulphuric acid consists of a doubly protonated Cinchona alkaloid strongly bound to a bisulphate HSO₄⁻ anion. This structure explains the lack of photo-reactivity of the complex upon UV irradiation.

Funder

Agence Nationale de la Recherche

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP01518C

Reference106 articles.

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