Palladium-catalyzed stereoselective ring-opening reaction of aryl cyclopropyl ketones-Reference-Cited by-同舟云学术

Palladium-catalyzed stereoselective ring-opening reaction of aryl cyclopropyl ketones

Published:2022 Issue:27 Volume:20 Page:5412-5415
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chen Yan-Zuo¹²,Wang Neng¹,Hou Zong-Rui¹,Zhou Xian-Li¹,Li Xiaohuan¹,Gao Feng¹^ORCID,Jiang Ting²

Affiliation:

1. Sichuan Engineering Research Center for Biomimetic Synthesis of Natural Drugs, School of Life Science and Engineering and College of Medicine, Southwest Jiaotong University, Chengdu 610031, PR China

2. Department of Pharmacy, The First Afflicted Hospital of Chengdu Medical College, Chengdu 610500, PR China

Abstract

The first palladium-catalyzed direct ring-opening of mono-substituted phenyl and heteroaryl cyclopropyl ketones to obtain α,β-unsaturated ketones is described. The reaction features high stereoselectivity to obtain (E)-1-phenylbut-2-en-1-one derivatives.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00719C

Reference31 articles.

1. Selective, Catalytic Carbon−Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts

2. Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes

3. Exploiting Heavier Organochalcogen Compounds in Donor–Acceptor Cyclopropane Chemistry

4. Selective Carbon–Carbon Bond Cleavage of Cyclopropanols

5. Transition Metal-Catalyzed Selective Carbon–Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. An Intermolecular Hydroarylation of Unactivated Arylcyclopropane via Re₂O₇/HFIP-Mediated Ring Opening;Organic Letters;2024-03-05