Hydrophosphorylation of aliphatic alkynes catalyzed by CuNPs/ZnO for the synthesis of vinyl phosphonates. A DFT study on the reaction mechanism-Reference-Cited by-同舟云学术

Hydrophosphorylation of aliphatic alkynes catalyzed by CuNPs/ZnO for the synthesis of vinyl phosphonates. A DFT study on the reaction mechanism

Published:2017 Issue:30 Volume:7 Page:18707-18713
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Fortunato Leandro¹²³⁴⁵^ORCID,Moglie Yanina¹²³⁴⁵^ORCID,Dorn Viviana¹²³⁴⁵^ORCID,Radivoy Gabriel¹²³⁴⁵^ORCID

Affiliation:

1. INQUISUR

2. Departamento de Química

3. Universidad Nacional del Sur (UNS)-CONICET

4. 8000 Bahía Blanca

5. Argentina

Abstract

A DFT study on the reaction mechanism for the synthesis of vinyl phosphonates catalyzed by CuNPs/ZnO. Essential role of the solvent and the catalyst support.

Funder

Secretaría General de Ciencia y Tecnología, Universidad Nacional del Sur

Consejo Nacional de Investigaciones Científicas y Técnicas

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01037K

Reference47 articles.

1. A Facile Route to Vinyl- and Arylphosphonates by Vinyl and Aryl Radical Trapping with (MeO)3P

2. Transition Metal-Promoted Syntheses of Vinylphosphonates

3. Conversion of Cyclic Vinyl Sulfones to Transposed Vinyl Phosphonates

4. Vinylphosphonates in Organic Synthesis

5. Strategies for the synthesis of α- and β-amino vinylphosphonate

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