Metal-free enantioselective addition of nucleophilic silicon to aromatic aldehydes catalyzed by a [2.2]paracyclophane-based N-heterocyclic carbene catalyst
Author:
Affiliation:
1. School of Pharmaceutical Sciences
2. Shandong University
3. Jinan 250012
4. P. R. China
5. Department of Chemistry
6. Jinan 250100
7. School of Chemistry and Chemical Engineering
8. Hebei Normal University For Nationalities
9. Chengde 0670000
Abstract
A transition metal-free enantioselective 1,2-silylation of aromatic aldehydes to yield chiral α-hydroxysilanes was developed for the first time.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00243B
Reference60 articles.
1. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
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4. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
5. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
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