The perfluoroalkylthiolation/decarbonylation reaction of 1,3-diketones with perfluoroalkanesulfenic acids

Author:

Li Jia-Hui12,Jiang Min2,Liu Jin-Tao12ORCID

Affiliation:

1. The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China

2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

Abstract

The perfluoroalkylthiolation/decarbonylation reactions of 1,3-dicarbonyl compounds with in situ formed perfluoroalkanesulfenic acids were achieved.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference47 articles.

1. Electrophilic Perfluoroalkylating Agents

2. Perfluoroalkylation with Organosilicon Reagents

3. Aromatic Trifluoromethylation with Metal Complexes

4. Catalysis for fluorination and trifluoromethylation

5. F. A.Carey and R. J.Sundberg , Nucleophilic Substitution , in Advanced Organic Chemistry: Part A: Structure and Mechanisms , ed. F. A. Carey and R. J. Sundberg , Springer US , Boston, MA , 2007

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