Nanoscale heterogeneity in thermoelectrics: the occurrence of phase separation in Fe-doped Ca3Co4O9

Author:

Xu Wei12345,Butt Sajid67895,Zhu Yingcai12345,Zhou Jing103115,Liu Yong12135,Yu Meijuan12345,Marcelli Augusto1415161718,Lan Jinle1920215,Lin Yuan-Hua67895,Nan Ce-Wen67895

Affiliation:

1. Beijing Synchrotron Radiation Facility

2. Institute of High Energy Physics

3. Chinese Academy of Sciences

4. Beijing 100049

5. P. R. China

6. State Key Laboratory of New Ceramics and Fine Processing

7. School of Materials Science and Engineering

8. Tsinghua University

9. Beijing 100084

10. Shanghai Institute of Applied Physics

11. Shanghai

12. AVIC Beijing Institute of Aeronautical Materials

13. Beijing 100095

14. RICMASS

15. Rome International Center for Materials Science Superstripes

16. 00185 Rome

17. Italy

18. INFN – Laboratori Nazionali di Frascati

19. State Key Laboratory of Organic–Inorganic Composites

20. Beijing University of Chemical Technology

21. Beijing 100029

Abstract

The thermoelectricity of Fe doped Ca3Co4O9 is tuned by nanoscale structural heterogeneity, as unveiled by X-ray absorption spectroscopy and density functional theory.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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