A mechanistic study of manganese(iii) acetate-mediated phosphonyl group additions to [60]- and [70]-fullerenes: the oxidative-ion-transfer mechanism vs. free radical addition-Reference-Cited by-同舟云学术

A mechanistic study of manganese(iii) acetate-mediated phosphonyl group additions to [60]- and [70]-fullerenes: the oxidative-ion-transfer mechanism vs. free radical addition

Published:2016 Issue:42 Volume:45 Page:16838-16849
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tumanskii Boris L.¹²³,Sabirov Denis S.⁴⁵³,Lyakhovetsky Yury I.¹²³^ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2. 119991 GSP-1 Moscow V-334

3. Russia

4. Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

5. 450075 Ufa

Abstract

The phosphonylation of fullerenes with HP(O)(OAlk)₂ and Mn(OAc)₃·2H₂O occurs via the oxidative-ion-transfer mechanism involving the intermediate Mn(OAc)₂P(O)(OAlk)₂ rather than by the free radical process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02941H

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5. M. D. Tzirakis and M.Orfanopoulos, in Encyclopedia of Radicals in Chemistry, Biology & Materials, ed. C. Chatgilialoglu and A. Studer, John Wiley & Sons, Ltd, Chichester, U.K., 2012, pp. 2171–2196

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