Hydrometallation of amino-trialkynylsilanes – intramolecular M–N interactions (M = Al, Ga) and potential activation of Si

Hydrometallation of amino-trialkynylsilanes – intramolecular M–N interactions (M = Al, Ga) and potential activation of Si–N bonds

Published:2014 Issue:38 Volume:43 Page:14386-14398
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Uhl Werner¹²,Bohnemann Jörg¹²,Kappelt Benedikt¹²,Hepp Alexander¹²,Layh Marcus¹²

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Universität Münster

2. D-48149 Münster, Germany

Abstract

Hydrometallation of amino-alkynylsilanes afforded highly functionalized alkenyl–alkynylsilanes with a fascinating diversity of intramolecular donor–acceptor interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00922C

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