Novel Fe(ii) spin crossover complexes involving a chalcogen-bond and π-stacking interactions with a paramagnetic and nonmagnetic M(dmit)2 anion (M = Ni, Au; dmit = 4,5-dithiolato-1,3-dithiole-2-thione)-Reference-Cited by-同舟云学术

Novel Fe(ii) spin crossover complexes involving a chalcogen-bond and π-stacking interactions with a paramagnetic and nonmagnetic M(dmit)2 anion (M = Ni, Au; dmit = 4,5-dithiolato-1,3-dithiole-2-thione)

Published:2015 Issue:30 Volume:3 Page:7858-7864
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Okai Mitsunobu¹²³⁴⁵,Takahashi Kazuyuki¹²³⁴⁵,Sakurai Takahiro⁶³⁴⁵,Ohta Hitoshi⁷³⁴⁵,Yamamoto Takashi¹⁸⁹⁵,Einaga Yasuaki¹⁸⁹⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kobe University

4. Kobe

5. Japan

6. Center for Supports to Research and Education Activities

7. Molecular Photoscience Research Center

8. Keio University

9. Yokohama

Abstract

A novel Fe(ii) complex with a π-radical anion exhibited a complete spin crossover transition with a stable paramagnetic state due to a strong chalcogen-bond and π-stacking interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/TC/C5TC00859J

Reference27 articles.

1. Molecular spin crossover phenomenon: recent achievements and prospects

2. Electrical Conductivity Modulation Coupled to a High-Spin−Low-Spin Conversion in the Molecular System [FeIII(qsal)2][Ni(dmit)2]3·CH3CN·H2O

3. Evidence of the Chemical Uniaxial Strain Effect on Electrical Conductivity in the Spin-Crossover Conducting Molecular System: [FeIII(qnal)2][Pd(dmit)2]5·Acetone

4. Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable-Temperature Electrical Conductivity

5. Spin-crossover behavior and electrical conduction property in iron(ii) complexes with tetrathiafulvalene moieties

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