Reversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation-Reference-Cited by-同舟云学术

Reversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation

Published:2016 Issue:5 Volume:6 Page:1320-1327
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Jongbloed L. S.¹²³⁴⁵,de Bruin B.¹²³⁴⁵,Reek J. N. H.¹²³⁴⁵,Lutz M.⁶⁷⁸⁵,van der Vlugt J. I.¹²³⁴⁵

Affiliation:

1. Homogeneous, Bioinspired & Supramolecular Catalysis

2. van 't Hoff Institute for Molecular Sciences

3. University of Amsterdam

4. 1098 XH Amsterdam

5. The Netherlands

6. Crystal & Structural Chemistry

7. Bijvoet Center for Biomolecular Research

8. Utrecht University

Abstract

The first example of base-free catalytic dehydrogenation of formic acid using reversible cyclometalation at Rh(i) is discussed, using a combination of experimental and computational methods.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY01505G

Reference93 articles.

1. New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

2. Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation

3. Redox-active ligands in catalysis

4. Cooperative Catalysis with First‐Row Late Transition Metals

5. Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

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