Carbon–fluorine and –hydrogen bond activation and carbon–carbon bond formation in η5-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; crystal structures of [M(η5-C5Me5)Cl{(C6F5)2PCH2CH2P(C6F5)2}]+BF4–(M = Rh or Ir)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960003215
Reference28 articles.
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3. An unexpected reaction between B(C6F5)3and [Fe(η5-C5H5)(CO)2Me] gives {[Fe-σ-C6F4(2-C(O)Me)](η5-C5H5)(CO)}
4. Homogeneous rhodium complex-catalyzed hydrogenolysis of C-F bonds.
5. Activation of carbon-fluorine bonds by oxidative addition
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