Reaction of the η2(4e)-donor alkyne complexes [Mo{η2(4e)-R1C2R2}{P(OMe)3}2(η-C5H5)](R1= R2= Ph or Me; R1= Me, R2= Ph) with the Grignard reagents MgR3(X)(R3= Me, Et, CH2Ph, CH2CHCH2or CHCH2) and CH2(MgI)2-Reference-Cited by-同舟云学术

Reaction of the η2(4e)-donor alkyne complexes [Mo{η2(4e)-R1C2R2}{P(OMe)3}2(η-C5H5)](R1= R2= Ph or Me; R1= Me, R2= Ph) with the Grignard reagents MgR3(X)(R3= Me, Et, CH2Ph, CH2CHCH2or CHCH2) and CH2(MgI)2

Published:1996 Issue:16 Volume: Page:3387-3396
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Brauers Georg,Feher Frank J.,Green Michael,Hogg John K.,Orpen A. Guy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960003387

Reference26 articles.

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2. Reactions of co-ordinated ligands. Part 33. Mononuclear η2-vinyl complexes: synthesis, structure, and reactivity

3. Reactions of co-ordinated ligands. Part 39. The synthesis of carbyne complexes from alkyne molybdenum and tungsten cations; formation and crystal structures of [Mo(CCH2But){P(OMe)3}2(η-C5H5)] and [Mo{C(SiMe3)CH2}{P(OMe)3}2(η5-C9H7)]

4. The role of α-hydrogen elimination reactions in the formation of η3-cyclopropenyl-and η4-cyclopentadiene-molybdenum complexes

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3. Molybdenum Compounds without CO or Isonitrile Ligands;Comprehensive Organometallic Chemistry III;2007

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