Controlled hydrolysis reactions of the Group 15 element–azamacrocyclic complexes MCl3L (M = As, Sb or Bi; L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Formation and crystal structures of [AsCl2L][As2OCl5], [H2L]2[Sb2OCl6]Cl2, [HL]I and [H2L]2[Sb2Cl9]Cl·MeCN·H2O
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960004045
Reference44 articles.
1. Azamacrocyclic complexation of bismuth(III): Formation and structure of fac-(BiCl3·Me3[9]aneN3) where Me3[9]aneN3 = 1,4,7-trimethyl-1,4,7-triazacyclononane
2. Stereochemical role of lone pairs in main-group elements. Part 3. Structure and bonding in trichloro(1,4,7,10,13-pentaoxacyclopentadecane)antimony(III) studied by means of X-ray crystallography at 120 K
3. Crown ether complexes of BiIII. Synthesis and crystal and molecular structures of BiCl3·12-crown-4 and 2BiCl3·18-crown-6
4. Stereochemical activity of lone pairs. The crystal and molecular structure of a complex of 18-crown-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) with bismuth(III) chloride
5. Synthesis and structure of antimony(III)chloride-1,4,7,10,13,16-hexaoxocyclooctadecane-(18-crown-6)-acetonitrile (1/1/1)
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