Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides
Author:
Affiliation:
1. Departamento de Química Inorgánica
2. Facultad de Química
3. Universidad de Murcia
4. 30100 Murcia
5. Spain
6. Área Científica y Técnica de Investigación
Abstract
The photochemical generation of isolable bis-cyclometalated Pt(iv) hydrides via photooxidative C–H addition reactions is demonstrated from easily accessible Pt(ii) precursors using visible light.
Funder
Ministerio de Ciencia, Innovación y Universidades
Fundación Séneca
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04879H
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5. Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes
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