Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution-Reference-Cited by-同舟云学术

Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution

Published:2015 Issue:9 Volume:3 Page:4827-4839
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Rosnes Mali H.¹²³⁴,Opitz Martin¹²³⁴,Frontzek Matthias⁵⁶⁷⁸,Lohstroh Wiebke⁹¹⁰¹¹¹²,Embs Jan Peter⁵⁶⁷⁸,Georgiev Peter A.¹¹³¹⁴¹⁵¹⁶,Dietzel Pascal D. C.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Bergen

3. N-5020 Bergen

4. Norway

5. Laboratory for Neutron Scattering and Imaging

6. Paul Scherrer Institut

7. CH-5232 Villigen

8. Switzerland

9. Heinz Maier-Leibnitz Zentrum (MLZ)

10. Technische Universität München

11. D-85748 Garching

12. Germany

13. University of Milan

14. 20133 Milano

15. Italy

16. Faculty of Chemistry and Pharmacy

Abstract

We present a comparative study of hydrogen gas adsorption experiments on CPO-27–Cu and –Mn. The initial isosteric heat of adsorption in CPO-27–Cu is low for a material containing open metal sites and in contrast to the other members of the CPO-27 series, including the Mn compound.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/TA/C4TA05794E

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3. A combined experimental and quantum chemical study of CO2 adsorption in the metal–organic framework CPO-27 with different metals