Canting angle dependence of single-chain magnet behaviour in chirality-introduced antiferromagnetic chains of acetate-bridged manganese(iii) salen-type complexes

Author:

Huang Po-Jung12345,Miyasaka Hitoshi12345ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

Abstract

An acetate-bridged Mn(iii) salen-type alternating chain exhibits slow relaxation of the magnetization categolized to single-chain magnet behavior. The canting motif of the Jahn–Teller axis on the Mn(iii) center is the key to obtain this behavior.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference45 articles.

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4. Glauber dynamics in a single-chain magnet: From theory to real systems

5. C. Coulon , H.Miyasaka and R.Clérac , in Single-chain magnets: theoretical approach and experimental systems , ed. R. E. P. Winpenny , Single-molecule magnets and related phenomena: structure and bonding , Springer , Berlin, Heidelberg , 2005 , vol. 122 , pp. 163–206

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