Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Natural Sciences
3. University of SS Cyril and Methodius
4. Slovakia
5. Institute of Inorganic Chemistry
6. Slovak University of Technology
7. Leibniz University
8. Germany
Abstract
A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).
Funder
Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
Agentúra na Podporu Výskumu a Vývoja
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03610B
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5. Spin crossover phenomena in Fe(ii) complexes
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