Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis-Reference-Cited by-同舟云学术

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

Published:2021 Issue:2 Volume:50 Page:472-475
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rajnák Cyril¹²³⁴^ORCID,Mičová Romana¹²³⁴,Moncoľ Ján⁵⁶⁴^ORCID,Dlháň Ľubor⁵⁶⁴,Krüger Christoph⁵⁷⁸,Renz Franz⁵⁷⁸^ORCID,Boča Roman¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Natural Sciences

3. University of SS Cyril and Methodius

4. Slovakia

5. Institute of Inorganic Chemistry

6. Slovak University of Technology

7. Leibniz University

8. Germany

Abstract

A pentadentate Schiff-base ligand ^3,5Cl-L²⁻ and NCSe⁻ form a iron(iii) mononuclear complex [Fe(^3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03610B

Reference52 articles.

1. Spin Transitions in six-coordinate iron(II) complexes

2. Spin crossover in iron(II)-complexes

3. Nature and dynamics of the spin-state interconversion in metal complexes

4. Thermisch und optisch schaltbare Eisen(II)-Komplexe

5. Spin crossover phenomena in Fe(ii) complexes

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