Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis-Reference-Cited by-同舟云学术

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

Published:2021 Issue:2 Volume:50 Page:472-475
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rajnák Cyril¹²³⁴^ORCID,Mičová Romana¹²³⁴,Moncoľ Ján⁵⁶⁴^ORCID,Dlháň Ľubor⁵⁶⁴,Krüger Christoph⁵⁷⁸,Renz Franz⁵⁷⁸^ORCID,Boča Roman¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Natural Sciences

3. University of SS Cyril and Methodius

4. Slovakia

5. Institute of Inorganic Chemistry

6. Slovak University of Technology

7. Leibniz University

8. Germany

Abstract

A pentadentate Schiff-base ligand ^3,5Cl-L²⁻ and NCSe⁻ form a iron(iii) mononuclear complex [Fe(^3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03610B

Reference52 articles.

1. Spin Transitions in six-coordinate iron(II) complexes

2. Spin crossover in iron(II)-complexes

3. Nature and dynamics of the spin-state interconversion in metal complexes

4. Thermisch und optisch schaltbare Eisen(II)-Komplexe

5. Spin crossover phenomena in Fe(ii) complexes

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Towards spin-crossover in pseudo-octahedral iron(III) complexes of strongly absorbing phenanthridine-based N^N^O- ligands;Inorganica Chimica Acta;2024-04

2. Synthesis, crystal structures and thermal properties of heteroleptic acetylacetonato iron(III) complexes with aromatic N,Ń-donor ligands;Inorganica Chimica Acta;2023-09

3. The cooperative effects of substituents and anions in Mn(III) spin crossover complexes with hexadentate Schiff-base ligands;Journal of Molecular Structure;2023-09

4. Spin crossover mediated by hydrogen bonds in iodine-substituted manganese complexes;Journal of Molecular Structure;2023-03

5. Variation of Spin-Transition Temperature in the Iron(III) Complex Induced by Different Compositions of the Crystallization Solvent;Crystal Growth & Design;2023-02-16