Corrole–ferrocene and corrole–anthraquinone dyads: synthesis, spectroscopy and photochemistry
Author:
Affiliation:
1. Inorganic & Physical Chemistry Division
2. CSIR-Indian Institute of Chemical Technology
3. Habsiguda Hyderabad-500007
4. India
5. Academy of Scientific and Innovative Research (AcSIR)
Abstract
Two different donor–acceptor systems based on corrole–ferrocene (Cor–Fc) and corrole–anthraquinone (Cor–AQ) have been designed and synthesized. Excited state properties of these dyads indicates intramolecular photoinduced electron transfer (PET) take place in these dyads and the electron-transfer rates (kET) was found to be ∼1011s−1. The charge separation (CS) and charge recombination (CR) are found to be identical.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP02565F
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