Electrophile-promoted Fe-to-N2 hydride migration in highly reduced Fe(N2)(H) complexes
Author:
Affiliation:
1. Division of Chemistry and Chemical Engineering
2. California Institute of Technology
3. Pasadena
4. USA
Abstract
An emerging challenge in nitrogen fixation catalysis is the formation of hydride species, which can play a role in catalyst deactivation and unproductive hydrogen evolution. A new pathway for productive N–H bond formation from an iron hydride precursor is described.
Funder
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02380H
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