Photocatalytic hydrogenation of acetophenone over Pd–TiO2 using saccharides as hydrogen sources

Author:

Oto Takahiro1,Ikeuchi Kazuma2,Tanaka Kosuke1,Onda Ayumu34,Imamura Kazuya34ORCID

Affiliation:

1. Graduate School of Integrated Arts and Sciences, Science and Technology Program, Chemistry and Biotechnology Course, Kochi University, 2-5-1, Akebono-cho, Kochi-shi, Kochi 780-8520, Japan

2. Graduate School of Integrated Arts and Sciences, Applied Science Program, Applied Chemistry Course, Kochi University, 2-5-1, Akebono-cho, Kochi-shi, Kochi 780-8520, Japan

3. Research and Education Faculty, Multidisciplinary Science Cluster, Interdisciplinary Science Unit, Kochi University, 2-5-1, Akebono-cho, Kochi-shi, Kochi 780-8520, Japan

4. Research Laboratory of Hydrothermal Chemistry, Faculty of Science and Technology, Kochi University, 2-5-1 Akebono-cho, Kochi 780-8520, Japan

Abstract

Acetophenone was converted to 1-phenylethanol over a Pd–TiO2 photocatalyst using various saccharides without the use of hydrogen gas, indicating that various saccharides can be used instead of hydrogen gas in this photocatalytic hydrogenation system.

Funder

Japan Society for the Promotion of Science

TOBE MAKI Scholarship Foundation

Publisher

Royal Society of Chemistry (RSC)

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