Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone

Author:

Lei Caijin1,Xiao Chuan2,Tang Jie1,Yang Hongwei1ORCID,Zhang Qinghua3ORCID,Cheng Guangbin1ORCID

Affiliation:

1. School of Chemical Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu, China

2. China Northern Industries Group Co., Ltd. (NORINCO GROUP), Beijing 100089, P. R. China

3. Northwestern Polytechnical University, China, No. 127, Youyi West Road, Xi’an City, Shanxi Province, 710068, China

Abstract

Hydroxylamine-substituted compound 2 possesses higher density (1.905 g cm−3), superior overall detonation properties (D = 9201 m s−1, P = 38.4 GPa), with better mechanical sensitivities (IS = 30 J, FS = 360 N) than those of RDX.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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