(2-Pyridyloxy)arsines as ligands in transition metal chemistry: a stepwise As(iii) → As(ii) → As(i) reduction-Reference-Cited by-同舟云学术

(2-Pyridyloxy)arsines as ligands in transition metal chemistry: a stepwise As(iii) → As(ii) → As(i) reduction

Published:2020 Issue:29 Volume:49 Page:10042-10051
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gericke Robert¹²³⁴^ORCID,Wagler Jörg¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Technische Universität Bergakademie Freiberg

3. D-09596 Freiberg

4. Germany

Abstract

2-Pyridyloxy bridged As^III–Ru^II-complexes were shown capable of reductively eliminating an As-bound substituent with formation of As^II–Ru^I and, upon coordinating AuCl at the vacant As lone pair, As^I–Ru^II complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01538E

Reference42 articles.

1. Coordination- and Redox-Noninnocent Behavior of Ambiphilic Ligands Containing Antimony

2. Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand

3. Sensing of Aqueous Fluoride Anions by Cationic Stibine-Palladium Complexes

4. From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

5. Synthesis and Structural Characterization of Novel Rhodium−Diacylarsenido Complexes

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