Dynamics of a gas-phase SNAr reaction: non-concerted mechanism despite the Meisenheimer complex being a transition state

Author:

Sharma Nishant12345,Biswas Rupayan12345,Lourderaj Upakarasamy12345ORCID

Affiliation:

1. School of Chemical Sciences

2. National Institute of Science Education and Research (NISER) Bhubaneswar

3. HBNI

4. Khurda

5. India

Abstract

Multi-step roaming pathway in the nucleophilic aromatic substitution reaction involving a Meisenheimer transition state.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference47 articles.

1. F. Terrier , Modern nucleophilic aromatic substitution , John Wiley & Sons , 2013

2. M. B. Smith and J.March , March's advanced organic chemistry: reactions, mechanisms, and structure , John Wiley & Sons , 2007

3. F. A. Carey and R. J.Sundberg , Advanced organic chemistry: part A: structure and mechanisms , Springer Science & Business Media , 2007

4. Concerted nucleophilic aromatic substitution with 19F− and 18F−

5. Concerted nucleophilic aromatic substitutions

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