Dynamics of a gas-phase SNAr reaction: non-concerted mechanism despite the Meisenheimer complex being a transition state
Author:
Affiliation:
1. School of Chemical Sciences
2. National Institute of Science Education and Research (NISER) Bhubaneswar
3. HBNI
4. Khurda
5. India
Abstract
Multi-step roaming pathway in the nucleophilic aromatic substitution reaction involving a Meisenheimer transition state.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05567K
Reference47 articles.
1. F. Terrier , Modern nucleophilic aromatic substitution , John Wiley & Sons , 2013
2. M. B. Smith and J.March , March's advanced organic chemistry: reactions, mechanisms, and structure , John Wiley & Sons , 2007
3. F. A. Carey and R. J.Sundberg , Advanced organic chemistry: part A: structure and mechanisms , Springer Science & Business Media , 2007
4. Concerted nucleophilic aromatic substitution with 19F− and 18F−
5. Concerted nucleophilic aromatic substitutions
Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Mechanistic insights into the challenges of organocatalytic Beckmann rearrangement reactions;Organic & Biomolecular Chemistry;2023
2. Reaction Space Projector (ReSPer) for Visualizing Dynamic Reaction Routes Based on Reduced-Dimension Space;Topics in Current Chemistry;2022-03-10
3. Influence of second-order saddles on reaction mechanisms;Faraday Discussions;2022
4. Fifty years of nucleophilic substitution in the gas phase;Mass Spectrometry Reviews;2021-05-31
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3