Reversion of catalyst valence states for highly efficient water oxidation

Author:

Huang Xiaolei12ORCID,Wang Fenghe3ORCID,Ma Lipo4,Wang Jiawei5,Zhang Tianyi1,Hao Xiaoyu1,Chi Xiao6,Cheng Hao7,Yang Ming7,Ding Jun8,Ang Diing Shenp2

Affiliation:

1. State Key Laboratory of Solidification Processing, Center of Advanced Lubrication and Seal Materials, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, P. R. China

2. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798, Singapore

3. Hebei Key Laboratory of Photo-Electricity Information and Materials, College of Physics Science and Technology, Hebei University, Baoding, Hebei 071002, PR China

4. Laboratory of Advanced Spectro-electrochemistry and Lithium-ion Batteries, Chinese Academy of Sciences, Dalian Institute of Chemical Physics, 457 Zhongshan Road, Dalian 116023, China

5. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, 7989 Weixing Road, Changchun 130012, China

6. Singapore Synchrotron Light Source, National University of Singapore, 5 Research Link, Singapore 117603, Singapore

7. Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China

8. Department of Materials Science and Engineering, National University of Singapore, Singapore 117576, Singapore

Abstract

An intermittent electrocatalytic mode for the oxygen evolution reaction (OER) inspired by the finding of room-temperature thermal reduction, and it reduces the OER overpotential significantly due to a reversible valence-change mechanism.

Funder

Natural Science Foundation of Hebei Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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