A fully diastereoselective oxidation of a mesoionic dipole with triplet molecular oxygen-Reference-Cited by-同舟云学术

A fully diastereoselective oxidation of a mesoionic dipole with triplet molecular oxygen

Published:2020 Issue:32 Volume:18 Page:6328-6339
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

García de la Concepción Juan¹²³⁴⁵^ORCID,Ávalos Martín¹²³⁴⁵^ORCID,Jiménez José L.¹²³⁴⁵^ORCID,Cintas Pedro¹²³⁴⁵^ORCID,Light Mark E.⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica

2. Facultad de Ciencias-UEX

3. and IACYS-Unidad de Química Verde y Desarrollo Sostenible

4. 06006 Badajoz

5. Spain

6. Department of Chemistry

7. Faculty of Natural and Environmental Sciences

8. University of Southampton

9. Southampton SO17 1BJ

10. UK

Abstract

A metal-free oxidation of a mesoionic dipole with atmospheric oxygen triggers a complex cascade reaction through spin intercrossing, as supported by computation, and leading to polycycles with complete diastereoselection.

Funder

Junta de Extremadura

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01428A

Reference48 articles.

1. E. T. Denisov and I. B.Afanas'ev , Oxidation and Antioxidants in Organic Chemistry and Biology , CRC Press, Inc. , Boca Raton, FL , 2005

2. J. McMurry and T.Begley , The Organic Chemistry of Biological Pathways , Roberts & Co. Publishers , Engelwood, CO , 2005 , pp. 34–36 , 148–153

3. P. M. Dewick , Medicinal Natural Products , John Wiley & Sons, Inc. , New York , 2nd edn, 2002 , pp. 24–28

4. Free radical mechanisms in autoxidation processes

5. Autoxidation of nonane and decane: a product study

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