Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized <i>via</i> collective interactions-Reference-Cited by-同舟云学术

Anti-electrostatic cation⋯π-hole and cation⋯lp-hole interactions are stabilized via collective interactions

Published:2024 Issue:4 Volume:60 Page:400-403
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pino-Rios Ricardo¹²,Báez-Grez Rodrigo³^ORCID,Foroutan-Nejad Cina⁴^ORCID

Affiliation:

1. Química y Farmacia, Facultad de Ciencias de la Salud, Universidad Arturo Prat., Casilla 121, Iquique 1100000, Chile

2. Instituto de Estudios de la Salud, Universidad Arturo Prat, Iquique, 1100000, Chile

3. Departamento de Química, Facultad de Ciencias Exactas, Universidad Andres Bello, Av. República 275, Santiago 8370146, Chile

4. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland

Abstract

The collective bonds are a non-Lewis type of bond forming between a σ-hole and an lp-hole or a π-hole through the interaction between the σ-hole and electron-rich substituents around the lp/π-hole.

Funder

Narodowe Centrum Nauki

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05451A

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5. Beyond the Classical Electron‐Sharing and Dative Bond Picture: Case of the Spin‐Polarized Bond