Amine-functionalized bifunctional Co<sup>III</sup>-NHC complexes: highly effective phosphine-free catalysts for the α-alkylation of nitriles-Reference-Cited by-同舟云学术

Amine-functionalized bifunctional Co^III-NHC complexes: highly effective phosphine-free catalysts for the α-alkylation of nitriles

Published:2024 Issue:23 Volume:60 Page:3142-3145
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Boity Biswaranjan¹,Sidiqque Misba¹,Rit Arnab¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India

Abstract

Robust bifunctional CoIII –complexes featuring amine-functionalized NHC ligands have been developed as highly effective catalysts for the nitrile α-alkylation with diverse alcohols, spanning from aliphatic to aromatic including the secondary ones.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05454C

Reference33 articles.

1. Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

2. Metal-Ligand Cooperation

3. Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

4. Synthesis of a-Alkylated Ketones via Tandem Acceptorless Dehydrogenation/a-Alkylation from Secondary and Primary Alcohols Catalyzed by Metal–Ligand Bifunctional Iridium Complex [Cp*Ir(2,2′-bpyO)(H2O)]

5. Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Recent Developments of Transition‐Metal‐Catalyzed Cross‐Coupling of Nitriles and Alcohols;ChemistrySelect;2024-08-22

2. Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation;Nature Communications;2024-08-15

3. Cobalt(III) Complexes of Pyridine-Functionalized Chelating NHC Ligands: Effective Catalysts for the Olefination of Alcohols Using Sulfones;Organometallics;2024-06-26