Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state-Reference-Cited by-同舟云学术

Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state

Published:2021 Issue:35 Volume:12 Page:11858-11863
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Smith Jordan N.¹²^ORCID,Ennis Courtney¹^ORCID,Lucas Nigel T.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Otago, Union Place, Dunedin, New Zealand

2. MacDiarmid Institute for Advanced Materials and Nanotechnology, New Zealand

Abstract

A robust, dimeric capsule forms quantitatively in low-polarity solvents via a seam of 8 hydrogen bonds. The resulting electron-rich cavity selectively binds small organic cations over neutral counterparts.

Funder

Royal Society Te Apārangi

MacDiarmid Institute for Advanced Materials and Nanotechnology

University of Otago

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01802G

Reference46 articles.

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2. Acceleration of a Diels–Alder reaction by a self-assembled molecular capsule

3. Catalysis inside the Hexameric Resorcinarene Capsule

4. Binding orientation and reactivity of alkyl α,ω-dibromides in water-soluble cavitands

5. A Synthetic Cavity Assembles Through Self-Complementary Hydrogen Bonds

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