Theoretical insights into the E1cB/E2 mechanistic dichotomy of elimination reactions-Reference-Cited by-同舟云学术

Theoretical insights into the E1cB/E2 mechanistic dichotomy of elimination reactions

Published:2019 Issue:46 Volume:17 Page:9874-9882
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ortega Daniela E.¹²³⁴^ORCID,Ormazábal-Toledo Rodrigo¹²³⁴^ORCID,Contreras Renato⁵⁶⁷⁸⁴^ORCID,Matute Ricardo A.¹²³⁴⁹^ORCID

Affiliation:

1. Centro Integrativo de Biología y Química Aplicada (CIBQA)

2. Universidad Bernardo O Higgins

3. Santiago 8370854

4. Chile

5. Departamento de Química

6. Facultad de Ciencias

7. Universidad de Chile

8. Santiago

9. Division of Chemistry and Chemical Engineering

Abstract

Modeling the E1cB, E2, and E1cB/E2 borderline mechanisms in terms of carbanion stabilization.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB02004G

Reference55 articles.

1. Stereochemical and base species dichotomies in olefin-forming E2 eliminations

2. R. A. Biggs and W. W.Ogilvie , in 6.18 Eliminations to Form Alkenes, Allenes, and Alkynes and Related Reactions , ed. P. Knochel , Elsevier , Amsterdam , 2014 , pp. 802–841

3. A. Krebs and J.Swienty-Busch , in 5.1 - Eliminations to Form Alkenes, Allenes and Alkynes and Related Reactions , ed. B. M. Trost and I. Fleming , Pergamon , Oxford , 1991 , pp. 949–973

4. How common are base-initiated, concerted 1,2 eliminations

5. Distinguishing between concerted and nonconcerted eliminations

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