Revisiting the origin of the bending in group 2 metallocenes AeCp<sub>2</sub> (Ae = Be

Revisiting the origin of the bending in group 2 metallocenes AeCp₂ (Ae = Be–Ba)

Published:2023 Issue:30 Volume:25 Page:20657-20667
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sergeieva Tetiana¹,Demirer T. Ilgin¹,Wuttke Axel²,Mata Ricardo A.²^ORCID,Schäfer André¹^ORCID,Linker Gerrit-Jan³,Andrada Diego M.¹^ORCID

Affiliation:

1. Department of Chemistry, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany

2. Institute for Physical Chemistry, Georg-August-University Göttingen, Tammannstrasse 6, D-37077 Göttingen, Germany

3. MESA+ Institute for Nanotechnology, University of Twente, 7522 NB Enschede, The Netherlands

Abstract

Metallocenes are well-established compounds in organometallic chemistry, which can exhibit either a coplanar structure or a bent structure according to the nature of the metal center (E) and cyclopentadienyl ligands (Cp).

Funder

European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05020J

Reference110 articles.

1. A New Type of Organo-Iron Compound

2. 114. Dicyclopentadienyliron

3. Cyclopentadien-Metallkomplexe, ein neuer Typ metallorganischer Verbindungen

4. X-RAY EXAMINATION OF IRON BISCYCLOPENTADIENYL

5. Bis-cyclopentadienyl Iron: a Molecular Sandwich

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