Ni(ii) and Co(ii) bis(acetylacetonato) complexes for alkene/vinylsilane silylation and silicone crosslinking-Reference-Cited by-同舟云学术

Ni(ii) and Co(ii) bis(acetylacetonato) complexes for alkene/vinylsilane silylation and silicone crosslinking

Published:2021 Issue:14 Volume:11 Page:4849-4856
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Puillet Magali¹²³⁴⁵,Delorme James¹²³⁴⁵,Crozet Delphine¹²³⁴⁵,Humbert Matthieu¹²³⁴⁵,Gajan David⁶⁴⁷⁸^ORCID,Bousquié Magali⁹¹⁰¹¹⁸,Blanc Delphine⁹¹⁰¹¹⁸,Raynaud Jean¹²³⁴⁵^ORCID,Monteil Vincent¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Catalysis

2. Polymerization, Processes and Materials

3. CP2M (UMR 5128, CNRS/Université de Lyon 1- Claude Bernard/CPE Lyon)

4. Université de Lyon

5. 69616 Villeurbanne cedex

6. Centre de Résonance Magnétique Nucléaire à Très Hauts champs (UMR 5082, CNRS/Ecole Normale Supérieure de Lyon/Université Claude Bernard Lyon 1)

7. 69100 Villeurbanne

8. France

9. Elkem Silicones

10. R&D Chemistry

11. 69192 Saint-Fons cedex

Abstract

Commercially available Ni(ii) and Co(ii) complexes – M(acac)₂ and M(tmhd)₂ – exhibit catalytic activity for alkene/vinylsilane dehydrogenative silylation (DS) and hydrosilylation (HS) with tertiary silanes without using any external reducing agents.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00834J

Reference41 articles.

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4. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

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