Role of peracetic acid on the disruption of lignin packing structure and its consequence on lignin depolymerisation

Author:

Ma Ruoshui1,Sanyal Udishnu23,Olarte Mariefel V.14ORCID,Job Heather M.1,Swita Marie S.1,Jones Susanne B.1,Meyer Pimphan A.1,Burton Sarah D.5,Cort John R.56ORCID,Bowden Mark E.5ORCID,Chen Xiaowen7,Wolcott Michael P.8ORCID,Zhang Xiao13ORCID

Affiliation:

1. Energy and Environment Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99354, USA

2. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99354, USA

3. Voiland School of Chemical Engineering & Bioengineering, Washington State University, Richland, WA, 99354, USA

4. Biological Systems Engineering, Washington State University, Pullman, WA 99164, USA

5. Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99354, USA

6. Institute of Biological Chemistry, Washington State University, Pullman, WA 99164, USA

7. National Bioenergy Centre, National Renewable Energy Lab, Golden, CO 80127, USA

8. Composite Materials Engineering Centre, Washington State University, Pullman, WA 99164, USA

Abstract

Peracetic acid is shown to delaminate the bulk lignin structure, resulting in volume expansion and improved accessibility to depolymerisation sites.

Funder

Bioenergy Technologies Office

Federal Aviation Administration

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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