Hexanuclear iron(iii) α-aminophosphonate: synthesis, structure, and magnetic properties of a molecular wheel

Author:

Doroshenko Iaroslav12345ORCID,Babiak Michal12345ORCID,Buchholz Axel678910ORCID,Tucek Jiri1112131415ORCID,Plass Winfried678910ORCID,Pinkas Jiri12345ORCID

Affiliation:

1. Department of Chemistry

2. Masaryk University

3. Kotlarska 2

4. CZ-61137 Brno

5. Czech Republic

6. Institut für Anorganische und Analytische Chemie

7. Friedrich-Schiller-Universität Jena

8. Humboldtstraße 8

9. 07743 Jena

10. Germany

11. Regional Centre of Advanced Technologies and Materials

12. Faculty of Science

13. Palacky University

14. Slechtitelu 27

15. CZ-78371 Olomouc

Abstract

A new hexanuclear molecular iron phosphonate complex, [Fe6(HAIPA)12(OH)6nH2O (1·nH2O) (H2AIPA = NH2(CH3)2CP(O)(OH)2, (2-aminopropan-2-yl)phosphonic acid), was synthesized from Fe2+ and Fe3+ salts in water by interaction with the ligand sodium salt.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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