Photoredox catalyzed hydroazolylation of alkenes <i>via</i> phosphoranyl radicals-Reference-Cited by-同舟云学术

Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals

Published:2024 Issue:10 Volume:11 Page:2839-2844
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhu Fan¹,Qiao Zhi¹,He Na¹,Nong Chunxiao¹,He Qiping¹,Xi Meilan²,Song Xizhong³²,Lin Jun¹^ORCID,Chen Jingbo¹^ORCID,Jin Yi¹^ORCID

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan Key Laboratory of Research & Development for Natural Products, School of Pharmacy, Yunnan University, Kunming, 650091, P. R. China

2. Jiangxi Fangzhu Pharmaceutical Co., Ltd., Xinyu 338000, P.R. China

3. State Key Laboratory of Southwestern Chinese Medicine Resources, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137, P.R. China

Abstract

A general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is reported. These reactions proceed via a phosphoranyl radical, followed by radical coupling of the resulting azole radical to the alkene radical.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00233D

Reference36 articles.

1. Copper-Catalyzed Regio- and Enantioselective Hydroamination of Alkenes with Hydroxylamines

2. Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

3. Late Transition Metal-Catalyzed Hydroamination and Hydroamidation

4. Anti-Markovnikov Intermolecular Hydroamination of Alkenes and Alkynes: A Mechanistic View

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