Cooperativity and coverage dependent molecular desorption in self-assembled monolayers: computational case study with coronene on Au(111) and HOPG-Reference-Cited by-同舟云学术

Cooperativity and coverage dependent molecular desorption in self-assembled monolayers: computational case study with coronene on Au(111) and HOPG

Published:2019 Issue:20 Volume:21 Page:10505-10513
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chilukuri Bhaskar¹²³⁴^ORCID,Mazur Ursula¹²³⁴^ORCID,Hipps K. W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Washington State University

3. Pullman

4. USA

Abstract

Molecular desorption energy in non-covalent SAMs is conventionally determined to be a solitary value. To the contrary, we show that the desorption energies are variable, coverage dependent and cooperative using coronene adsorbate and HOPG, Au(111) substrates.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP01774G

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1. Formation and Structure of Self-Assembled Monolayers

2. Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology

3. Self-assembled monolayers in organic electronics